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Author(s):   Imrik, K.; Farkas, E.; Vasvari, G.; Szilagyi, I.; Sarzynski, D.; Dobe, S.; Berces, T.; Marta, F.
Title:   Laser spectrometry and kinetics of selected elementary reactions of the acetonyl radical
Journal:   Phys. Chem. Chem. Phys.
Volume:   6
Page(s):   3958 - 3968
Year:   2004
Reference type:   Journal article
Squib:   2004IMR/FAR3958-3968

Reaction:   CH3C(O)CH2(·) + O2 → Products
Reaction order:   2
Temperature:   298 K
Pressure:  2.85E-3 bar
Rate expression:   3.49x10-13 [±5.1x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Laser induced fluorescence
Comments:   Reported error limits are 2 sigma. The most likely product is the CH3COCH2OO adduct.

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