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Author(s):   Jimenez, E.; Gierczak, T.; Stark, H.; Burkholder, J.B.; Ravishankara, A.R.
Title:   Reaction of OH with HO2NO2 (peroxynitric acid): Rate coefficients between 218 and 335 K and product yields at 298 K
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   1139 - 1149
Year:   2004
Reference type:   Journal article
Squib:   2004JIM/GIE1139-1149

Reaction:   ·OH + HO2NO2HO2 + HNO3
Reaction order:   2
Reference reaction:   ·OH + HO2NO2 → Products
Reference reaction order:   2
Temperature:   298 K
Rate expression:   1.0x10-1
Rate constant is an upper limit.
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Nitric oxide (NO) used to convert HO2to detectable OH.

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