Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Kiefer, J.H.; Katopodis, C.; Santhanam, S.; Srinivasan, N.K.; Tranter, R.S.
Title:   A shock-tube, laser-schlieren study of the dissociation of 1,1,1-trifluoroethane: An intrinsic non-RRKM process
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   2443 - 2450
Year:   2004
Reference type:   Journal article
Squib:   2004KIE/KAT2443-2450

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Temperature:   1600 - 2400 K
Pressure:  2.00E-2 - 0.73 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Laser schlieren
Comments:   Individual rate constant values are given in grafic format (plots) but are not reported as numeric values. The rate constant is in deep falloff but shows little variation with pressure. The authors assert that the results demonstrate an intrinsically non-RRKM behavior of the reaction.

View full bibliographic record.