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Author(s):   Le Crane, J.P.; Villenave, E.; Hurley, M.D.; Wallington, T.J.; Nishida, S.; Takahashi, K.; Matsumi, Y.
Title:   Atmospheric chemistry of pivalaldehyde and isobutyraldehyde: Kinetics and mechanisms of reactions with Cl atoms, fate of (CH3)3CC(O) and (CH3)2CHC(O) radicals, and self-reaction kinetics of (CH3)3CC(O)O2 and (CH3)2CHC(O)O2 radicals
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   795 - 805
Year:   2004
Reference type:   Journal article
Squib:   2004LEC/VIL795-805

Reaction:   tert-C4H9Cl + Cl → Products
Reaction order:   2
Reference reaction:   C2H4 + Cl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  7.00E-3 bar
Rate expression:   1.31x10-11±1.7x10-12
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Reference rate constant is (9.29 ± 0.93) x 10-11 CM3 s-1

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