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Author(s):   Martinez, E.; Aranda, A.; Diaz-De-Mera, Y.; Rodriguez, A.; Rodriguez, D.; Notario, A.
Title:   Mechanistic and kinetic study of the gas-phase reaction of atomic chlorine with cyclohexanone using an absolute and a relative technique; Influence of temperature
Journal:   J. Atmos. Chem.
Volume:   48
Page(s):   283 - 299
Year:   2004
Reference type:   Journal article
Squib:   2004MAR/ARA283-299

Reaction:   (CH3)2CO + Cl → Products
Reaction order:   2
Reference reaction:   C2H5Cl + Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.2x10-12±1.4x10-13
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography
Comments:   Reference rate constant was 6.8e-12 cm3molecule-1s-1.

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