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Author(s):   McCunn, L.R.; Krisch, M.J.; Takematsu, K.; Butler, L.J.; Shu, J.N.
Title:   Competing pathways in the 248 nm photodissociation of propionyl chloride and the barrier to dissociation of the propionyl radical
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   7889 - 7894
Year:   2004
Reference type:   Journal article
Squib:   2004MCC/KRI7889-7894

Reaction:   CH3CH2COCO + ·C2H5
Reaction order:   1
Rate expression:   no rate data available
Category:  Experiment
Data type:   Data too complex to abstract
Pressure dependence:   None reported
Experimental procedure:   Other
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   No rate constant data were reported. Barrier for dissociation was estimated by determining the internal energy distribution of the undissociated radicals.

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