Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   McCunn, L.R.; Krisch, M.J.; Takematsu, K.; Butler, L.J.; Shu, J.N.
Title:   Competing pathways in the 248 nm photodissociation of propionyl chloride and the barrier to dissociation of the propionyl radical
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   7889 - 7894
Year:   2004
Reference type:   Journal article
Squib:   2004MCC/KRI7889-7894

Reaction:   CH3CH2COCO + ·C2H5
Reaction order:   1
Rate expression:   no rate data available
Category:  Experiment
Data type:   Data too complex to abstract
Pressure dependence:   None reported
Experimental procedure:   Other
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   No rate constant data were reported. Barrier for dissociation was estimated by determining the internal energy distribution of the undissociated radicals.

View full bibliographic record.