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Author(s):   Vandresen, S.; Resende, S.M.
Title:   The atmospheric reaction between DMSO and the chlorine radical
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   2284 - 2289
Year:   2004
Reference type:   Journal article
Squib:   2004VAN/RES2284-2289

Reaction:   (CH3)2SO + ·ClCH3Cl + CH3S(O)
Reaction order:   2
Rate expression:   no rate data available
Category:  Theory
Data type:   Barrier height only calculated
Comments:   CBS procedure using MP2 geometries and frequencies, CCSD(T)/6-31G(d,p) calculation and additivity method, rates via conventional TST, Arrhenius parameters for each microchannel are given. This reaction channel is predicted to be negligible due to a high barrier.

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