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Author(s):   Andersen, M.P.; Nielsen, O.J.; Wallington, T.J.; Hurley, M.D.
Title:   Atmospheric chemistry of CF3OCF2CF2H and CF3OC(CF3)2H: Reaction with Cl atoms and OH radicals, degradation mechanism, global warming potentials, and empirical relationship between k(OH) and k(Cl) for organic compounds
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   3926 - 3934
Year:   2005
Reference type:   Journal article
Squib:   2005AND/NIE3926-3934

Reaction:   CF3OCF2CHF2 + ·OH → Products
Reaction order:   2
Reference reaction:   C2H4 + ·OH → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   2.61x10-4±1.9x10-5
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Relative rate studies were performed in a 140-liter Pyrex reactor. The authors used this relatvie rate to derive absolute values using k(OH + C2H4) = 8.66 x 10-12 cm3 molecule-1 s-1 [Calvert, J. G.; Atkinson, R.; Kerr, J. A.; Madronich, S.; Moortgat, G. K.; Wallington, T. J.; Yarwood, G. Mechanisms of the Atmospheric Oxidation of the Alkenes; Oxford University Press: Oxford, U.K., 2000; ISBN 0-19-513177-0.]

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