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Author(s):   Becerra, R.; Boganov, S.E.; Egorov, M.P.; Krylova, I.V.; Nefedov, O.M.; Walsh, R.
Title:   Direct detection of chlorosilylene and time resolved study of some of its reactions in the gas-phase using a new photochemical precursor
Journal:   Chem. Phys. Lett.
Volume:   413
Page(s):   194 - 200
Year:   2005
Reference type:   Journal article
Squib:   2005BEC/BOG194-200

Reaction:   CH3GeH3 + SiHCl → Products
Reaction order:   2
Temperature:   299 K
Pressure:  1.33E-2 - 4.00E-2 bar
Rate expression:   6.61x10-14 [±8.0x10-15 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Up to 30 Torr of CH3GeH3 was used; total pressure was not kept constant during the experiment.

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