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Author(s):   Canosa-Mas, C.E.; Flugge, M.L.; King, M.D.; Wayne, R.P.
Title:   An experimental study of the gas-phase reaction of the NO3 radical withα,β-unsaturated Carbonyl compounds
Journal:   Phys. Chem. Chem. Phys.
Volume:   7
Page(s):   643 - 650
Year:   2005
Reference type:   Journal article
Squib:   2005CAN/FLU643-650

Reaction:   (E)-CH3C(O)CH=CHCH3 + NO3 → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.03x10-14 [±3.1x10-15 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   NO3 produced by the thermal decomposition of N2O5
Using k(NO3 + C3H6) = (9.5±1.1)x10-15cm3s-1.

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