Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Chen, H.B.; Thweatt, W.D.; Wang, J.J.; Glass, G.P.; Curl, R.F.
Title:   IR kinetic spectroscopy investigation of the CH4+O(1D) reaction
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   2207 - 2216
Year:   2005
Reference type:   Journal article
Squib:   2005CHE/THW2207-2216

Reaction:   O(1D) + CH4·CH3 + ·OH
Reaction order:   2
Reference reaction:   O(1D) + CH4 → Products
Reference reaction order:   2
Pressure:  8.80E-2 bar
Rate expression:   6.7x10-1±5.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Other (IR)
Comments:   O1D generated by the 193-nm photolysis of either N2O or NO2
Infrared kinetics spectroscopy used to measure the yields of OH, CH3, H2CO, CH3O, H2O and, after conversion to OH, H.

View full bibliographic record.