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Author(s):   Chen, H.B.; Thweatt, W.D.; Wang, J.J.; Glass, G.P.; Curl, R.F.
Title:   IR kinetic spectroscopy investigation of the CH4+O(1D) reaction
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   2207 - 2216
Year:   2005
Reference type:   Journal article
Squib:   2005CHE/THW2207-2216

Reaction:   O(1D) + CH4 → Other Products +
Reaction order:   2
Reference reaction:   O(1D) + CH4 → Products
Reference reaction order:   2
Pressure:  8.80E-2 bar
Rate expression:   3.0x10-1±1.0x10-1
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Other (IR)
Comments:   O1D generated by the 193-nm photolysis of either N2O or NO2
Infrared kinetics spectroscopy used to measure the yields of OH, CH3, H2CO, CH3O, H2O and, after conversion to OH, H.

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