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Author(s):   Gola, A.A.; D'Anna, B.; Feilberg, K.L.; Sellevag, S.R.; Bache-Andreassen, L.; Nielsen, C.J.
Title:   Kinetic isotope effects in the gas phase reactions of OH and Cl with CH3Cl, CD3Cl, and (CH3Cl)-C-13
Journal:   Atmos. Chem. Phys.
Volume:   5
Page(s):   2395 - 2402
Year:   2005
Reference type:   Journal article
Squib:   2005GOL/DAN2395-2402

Reaction:   CH3Cl + ·Cl → Products
Reaction order:   2
Reference reaction:   [13]CH3Cl + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   1.07±1.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Cl atoms produced by the photolysis of Cl2.

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