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Accessibility information
Author(s):   Kungwan, N.; Truong, T.N.
Title:   Kinetics of the hydrogen abstraction center dot CH3 plus alkane -> CH4 plus alkyl reaction class: An application of the reaction class transition state theory
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   7742 - 7750
Year:   2005
Reference type:   Journal article
Squib:   2005KUN/TRU7742-7750

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
    2005KUN/TRU7742-7750   CH4 + ·CH3CH4 + ·CH3  300 - 2500                  2
    2005KUN/TRU7742-7750   C2H6 + ·CH3CH4 + ·C2H5  300 - 2500                  2
    2005KUN/TRU7742-7750   C3H8 + ·CH3CH4 + 1-C3H7  300 - 2500                  2
    2005KUN/TRU7742-7750   C3H8 + ·CH3CH4 + iso-C3H7  300 - 2500                  2
    2005KUN/TRU7742-7750   1-C4H10 + ·CH3CH4 + 1-C4H9  300 - 2500                  2
    2005KUN/TRU7742-7750   1-C4H10 + ·CH3CH4 + sec-C4H9  300 - 2500                  2
    2005KUN/TRU7742-7750   iso-C4H10 + ·CH3CH4 + iso-C4H9  300 - 2500                  2
    2005KUN/TRU7742-7750   iso-C4H10 + ·CH3CH4 + tert-C4H9  300 - 2500                  2
    2005KUN/TRU7742-7750   n-C5H12 + ·CH3CH4 + 1-C5H11  300 - 2500                  2
    2005KUN/TRU7742-7750   n-C5H12 + ·CH3CH4 + CH3CH2CH2CH(·)CH3  300 - 2500                  2
    2005KUN/TRU7742-7750   n-C5H12 + ·CH3CH4 + (CH3CH2)2CH  300 - 2500                  2
    2005KUN/TRU7742-7750   neo-C5H12 + ·CH3CH4 + Neopentyl  300 - 2500                  2
    2005KUN/TRU7742-7750   iso-C5H12 + ·CH3CH4 + (CH3)2CHCH2CH2·  300 - 2500                  2
    2005KUN/TRU7742-7750   iso-C5H12 + ·CH3CH4 + (CH3)2CHCH(·)CH3  300 - 2500                  2
    2005KUN/TRU7742-7750   iso-C5H12 + ·CH3CH4 + (CH3)2C(·)CH2CH3  300 - 2500                  2
    2005KUN/TRU7742-7750   iso-C5H12 + ·CH3CH4 + ·CH2CH(CH3)CH2CH3  300 - 2500                  2

Search returned 16 records.