Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Lau, K.C.; Liu, Y.; Butler, L.J.
Title:   Probing the barrier for CH2CHCO -> CH2CH+CO by the velocity map imaging method
Journal:   J. Chem. Phys.
Volume:   123
Page(s):  
Year:   2005
Reference type:   Journal article
Squib:   2005LAU/LIU54322

Reaction:   CH2=CHC(·)OCO + C2H3
Reaction order:   1
Rate expression:   0.0 [s-1] e-87864 [±8368 J/mole]/RT
Category:  Other
Data type:   Other
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Other
Comments:   The dissociation barrier height for CH2CHCO -> CH2CH+CO reaction was determined experimentally using two-dimensional product velocity map imaging. Rate constants were not determined. CH2CHCO radicals were produced from the photodissociation of acryloyl chloride CH2CHCOCl at 193 nm.

View full bibliographic record.