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Author(s):   Lau, K.C.; Liu, Y.; Butler, L.J.
Title:   Probing the barrier for CH2CHCO -> CH2CH+CO by the velocity map imaging method
Journal:   J. Chem. Phys.
Volume:   123
Year:   2005
Reference type:   Journal article
Squib:   2005LAU/LIU54322

Reaction:   CH2=CHC(·)OCO + C2H3
Reaction order:   1
Rate expression:   0.0 [s-1] e-87864 [±8368 J/mole]/RT
Category:  Other
Data type:   Other
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Other
Comments:   The dissociation barrier height for CH2CHCO -> CH2CH+CO reaction was determined experimentally using two-dimensional product velocity map imaging. Rate constants were not determined. CH2CHCO radicals were produced from the photodissociation of acryloyl chloride CH2CHCOCl at 193 nm.

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