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Author(s):   Le Crane, J.P.; Villenave, E.; Hurley, M.D.; Wallington, T.J.; Ball, J.C.
Title:   Atmospheric chemistry of propionaldehyde: Kinetics and mechanisms of reactions with OH radicals and Cl atoms, UV spectrum, and self-reaction kinetics of CH3CH2C(O)O-2 radicals at 298 K
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   11837 - 11850
Year:   2005
Reference type:   Journal article
Squib:   2005LEC/VIL11837-11850

Reaction:   C2H5COCl + ·Cl → Products
Reaction order:   2
Reference reaction:   HC(O)OCH3 + ·Cl → Products
Reference reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.2±6.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Cl atoms produced by photolysis of Cl2.

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