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Author(s):   Mullen, C.; Smith, M.A.
Title:   Temperature dependence and kinetic isotope effects for the OH+HBr reaction and H/D isotopic variants at low temperatures (53-135 k) measured using a pulsed supersonic laval nozzle flow reactor
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   3893 - 3902
Year:   2005
Reference type:   Journal article
Squib:   2005MUL/SMI3893-3902

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2005MUL/SMI3893-3902   ·OH + HBrH2O + Br·  53.00 - 135   1.08E-11   -0.67          2
  2005MUL/SMI3893-3902   HBr + ODBr· + HDO  53.00 - 135   6.43E-12   -1.19          2
  2005MUL/SMI3893-3902   ·OH + DBrBr· + HDO  53.00 - 135   5.89E-12   -1.19          2
  2005MUL/SMI3893-3902   DBr + ODD2O + Br·  53.00 - 135   4.71E-12   -1.09          2

Search returned 4 records.