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Author(s):   Orlando, J.J.; Tyndall, G.S.; Betterton, E.A.; Lowry, J.; Lowry, J.; Stegall, S.T.
Title:   Atmospheric chemistry of hydrazoic acid (HN3): UV absorption spectrum, HO reaction rate, and reactions of the N3 radical
Journal:   Environ. Sci. Technol.
Volume:   39
Page(s):   1632 - 1640
Year:   2005
Reference type:   Journal article
Squib:   2005ORL/TYN1632-1640

Reaction:   CO + ·N3N2 + NCO
Reaction order:   2
Reference reaction:   NO + ·N3N2 + N2O
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.93 - 0.96 bar
Rate expression:   1.0x10-2
Rate constant is an upper limit.
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   N3 formed by reaction of Cl with HN3.
NO and CO were added in ratios of [NO]:[CO] = 1:1 to 1:25. This was expected to result in an increase in CO2 from
NOC + NO «rarrow» CO2 + N2
but no CO2 production was observed.

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