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Author(s):   Oyaro, N.; Sellevag, S.R.; Nielsen, C.J.
Title:   Atmospheric chemistry of hydrofluoroethers: Reaction of a series of hydrofluoro ethers with OH radicals and Cl atoms, atmospheric lifetimes, and global warming potentials
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   337 - 346
Year:   2005
Reference type:   Journal article
Squib:   2005OYA/SEL337-346

Reaction:   CF3CH2OCH3 + ·OH → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01E-2 bar
Rate expression:   5.7x10-13 [±8.0x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   OH radicals generated by the photolysis of O3/H2 mixtures.

Rate constant put on absolute basis using k(OH + CHCl3) = 1.00±0.15 x 10-13 cm3s-1 and k(OH + CH3C(O)CH3) = 1.80±0.45 x 10-13 cm3s-1.

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