Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help

Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

NIST home page

MML home page

Chemical Sciences Division
  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Pfrang, C.; Martin, R.S.; Nalty, A.; Waring, R.; Canosa-Mas, C.E.; Wayne, R.P.
Title:   Gas-phase rate coefficients for the reactions of nitrate radicals with (Z)-pent-2-ene, (E)-pent-2-ene, (Z)-hex-2-ene, (E)-hex-2-ene, (Z)-hex-3-ene, (E)-hex-3-ene and (E)-3-methylpent-2-ene at room temperature
Journal:   Phys. Chem. Chem. Phys.
Volume:   7
Page(s):   2506 - 2512
Year:   2005
Reference type:   Journal article
Squib:   2005PFR/MAR2506-2512

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2005PFR/MAR2506-2512   2-(Z)-C5H10 + NO3 → Products  300   1.73              2
  Reference reaction:  (E)-2-C4H8 + NO3 → Products 2
  2005PFR/MAR2506-2512   2-(E)-C5H10 + NO3 → Products  300   1.00              2
  Reference reaction:  (E)-2-C4H8 + NO3 → Products 2
  2005PFR/MAR2506-2512   (Z)-2-C6H12 + NO3 → Products  300   1.40              2
  Reference reaction:  (E)-2-C4H8 + NO3 → Products 2
  2005PFR/MAR2506-2512   (E)-2-C6H12 + NO3 → Products  300   1.01              2
  Reference reaction:  (E)-2-C4H8 + NO3 → Products 2
  2005PFR/MAR2506-2512   (Z)-3-C6H12 + NO3 → Products  300   1.13              2
  Reference reaction:  (E)-2-C4H8 + NO3 → Products 2
  2005PFR/MAR2506-2512   NO3 + (E)-3-C6H12 → Products  300   0.95              2
  Reference reaction:  (E)-2-C4H8 + NO3 → Products 2
  2005PFR/MAR2506-2512   (E)-CH3CH=C(CH3)C2H5 + NO3 → Products  300   0.86              2
  Reference reaction:  (CH3)2C=CHCH3 + NO3 → Products 2
  2005PFR/MAR2506-2512   (E)-CH3CH=C(CH3)C2H5 + NO3 → Products  300   8.90E-12              2
  2005PFR/MAR2506-2512   NO3 + (E)-3-C6H12 → Products  300   3.61E-13              2
  2005PFR/MAR2506-2512   (Z)-3-C6H12 + NO3 → Products  300   4.37E-13              2
  2005PFR/MAR2506-2512   (E)-2-C6H12 + NO3 → Products  300   3.83E-13              2
  2005PFR/MAR2506-2512   (Z)-2-C6H12 + NO3 → Products  300   5.30E-13              2
  2005PFR/MAR2506-2512   2-(E)-C5H10 + NO3 → Products  300   3.78E-13              2
  2005PFR/MAR2506-2512   2-(Z)-C5H10 + NO3 → Products  300   6.55E-13              2
Search returned 14 records.