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Author(s):   Rotinov, A.; Dominguez, R.M.; Cordova, T.; Chuchani, G.
Title:   Kinetics and mechanisms of the elimination of ethyl and tert-butyl esters of carbazic acid in the gas phase: experimental and theoretical studies
Journal:   J. Phys. Org. Chem.
Volume:   18
Page(s):   616 - 624
Year:   2005
Reference type:   Journal article
Squib:   2005ROT/DOM616-624

Reaction:   H2NNHCOOCH2CH3C2H5NH2 + CO + HNO
Reaction order:   1
Temperature:   493 - 615 K
Pressure:  2.81E-2 - 9.33E-2 bar
Rate expression:   6.92x1011 [±4.56x1011 s-1] e-176200 [±2500 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
493 1.54E-7
500 2.71E-7
525 2.04E-6
550 1.28E-5
575 6.82E-5
600 3.17E-4
615 7.44E-4