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Author(s):   Sun, T.L.; Zhang, Q.Z.; Qu, X.H.; Wang, W.X.
Title:   Mechanism and direct dynamics studies for the reaction of monoethylsilane EtSiH3 with atomic O(3P)
Journal:   Chem. Phys. Lett.
Volume:   407
Page(s):   527 - 532
Year:   2005
Reference type:   Journal article
Squib:   2005SUN/ZHA527-532

Reaction:   C2H5SiH3 + ·OH + C2H5SiH2(·)
Reaction order:   2
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Comments:   Reaction potential energy surface of the O + CH3CH2SiH3 reaction was studied using quantum chemistry and rate constants were calculated using variational transition state theory with tunneling correction. Abstraction of H from the SiH3 group is the dominant channel. Arrhenius expression is given for the overall reaction (three abstraction channels) but rate constants for individual channels are presented only in a tabular format.

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