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Accessibility information
Author(s):   Vasudevan, V.; Davidson, D.F.; Hanson, R.K.
Title:   High-temperature measurements of the reactions of OH with toluene and acetone
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   3352 - 3359
Year:   2005
Reference type:   Journal article
Squib:   2005VAS/DAV3352-3359

Reaction:   (CH3)2CO + ·OHCH3C(O)CH2(·) + H2O
Reaction order:   2
Temperature:   982 - 1300 K
Pressure:  1.54 - 1.82 bar
Rate expression:   4.9x10-11 [cm3/molecule s] e-19098 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
982 4.72E-12
1000 4.93E-12
1025 5.21E-12
1050 5.50E-12
1075 5.78E-12
1100 6.07E-12
1125 6.36E-12
1150 6.65E-12
1175 6.94E-12
1200 7.22E-12
1225 7.51E-12
1250 7.80E-12
1275 8.08E-12
1300 8.37E-12