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Author(s):   Wojcik-Pastuszka, D.; Gola, A.; Ratajczak, E.
Title:   Gas phase kinetics of the reaction system of 2NO«lrarrow» N2O4 and simple alcohols between 293-358 K
Journal:   Polish J. Chem.
Volume:   79
Page(s):   1301 - 1313
Year:   2005
Reference type:   Journal article
Squib:   2005WOJ/GOL1301-1313

Reaction:   CH3OH + N2O4CH3ONO + HNO3
Reaction order:   2
Temperature:   298 K
Pressure:  0.50 bar
Rate expression:   3.0x10-18 [±9.0x10-19 cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Reaction was studied in the 291 - 358 K temperature range. However, only 298 K value of the rate constant and the activation energy (3.9 +/- 3.7 kJ/mol) are reported. The preexponential factor is not reported. Rate constants at individual temperatures are given in a tabular format.

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