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Title: Gas phase kinetics of the reaction system of 2NO«lrarrow» N2O4 and simple alcohols between 293-358 K
Journal: Polish J. Chem.
Volume: 79
Page(s): 1301 - 1313
Year: 2005
Reference type: Journal article
Squib: 2005WOJ/GOL1301-1313
Reaction:
C2H5OH + N2O4 → C2H5ONO + HNO3
Reaction order:
2
Temperature:
298
K
Pressure: 0.50 bar
Rate expression:
8.0x10-18 [±2.4x10-18 cm3/molecule s]
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
Comments:
Reaction was studied in the 320 - 358 K temperature range. However, only 298 K value of the rate constant and the activation energy (5.5 +/- 5.0 kJ/mol) are reported. The preexponential factor is not reported. Rate constants at individual temperatures are given in a tabular format.
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