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Author(s):   Yeung, L.Y.; Pennino, M.J.; Miller, A.M.; Elrod, M.J.
Title:   Kinetics and mechanistic studies of the atmospheric oxidation of alkynes
Journal:   J. Phys. Chem. A
Volume:   109
Page(s):   1879 - 1889
Year:   2005
Reference type:   Journal article
Squib:   2005YEU/PEN1879-1889

Reaction:   CH3CCCH3 + ·OH + O2 → Products
Reaction order:   3
Temperature:   298 K
Pressure:  0.13 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   OH generated by reaction of F with H2O.
Production of biacetyl and acetic acid observed. Neither the 2-butyne-derived vinoxy radical nor hydroxy peroxy radical were observed.

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