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Accessibility information
Author(s):   Aschmann, S.M.;Long, W.D.;Atkinson, R.
Title:   Temperature-dependent rate constants for the gas-phase reactions of OH radicals with 1,3,5-trimethylbenzene, triethyl phosphate, and a series of alkylphosphonates
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   7393 - 7400
Year:   2006
Reference type:   Journal article
Squib:   2006ASC/LON7393-7400

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006ASC/LON7393-7400   (CH3O)2P(O)CH3 + ·OH → Products  278 - 348   8.00E-14       -1.22E04   1.11E-11  2
  2006ASC/LON7393-7400   ·OH + (CH3O)2P(O)C2H5 → Products  278 - 348   9.76E-14       -1.26E04   1.60E-11  2
  2006ASC/LON7393-7400   (C2H5O)2P(O)CH3 + ·OH → Products  278 - 348   4.20E-13       -1.21E04   5.56E-11  2
  2006ASC/LON7393-7400   (C2H5O)3P + ·OH → Products  278 - 348   6.46E-13       -1.11E04   5.78E-11  2
  2006ASC/LON7393-7400   (C2H5O)3PO + ·OH → Products  278 - 348   4.29E-13       -1.19E04   5.17E-11  2
  2006ASC/LON7393-7400   1,3,5-Trimethylbenzene + ·OH → Products  278 - 348   4.40E-12       -6136   5.24E-11  2
    2006ASC/LON7393-7400   (n-C4H9)2O + ·OH → Products                     2
  Reference reaction:  alpha-pinene + ·OH → Products 2
  2006ASC/LON7393-7400   (n-C4H9)2O + ·OH → Products  297   2.72              2
  Reference reaction:  1-C10H22 + ·OH → Products 2
    2006ASC/LON7393-7400   1,3,5-Trimethylbenzene + ·OH → Products                     2
  Reference reaction:  alpha-pinene + ·OH → Products 2
    2006ASC/LON7393-7400   (C2H5O)3PO + ·OH → Products                     2
  Reference reaction:  alpha-pinene + ·OH → Products 2
    2006ASC/LON7393-7400   (C2H5O)2P(O)CH3 + ·OH → Products                     2
  Reference reaction:  alpha-pinene + ·OH → Products 2
    2006ASC/LON7393-7400   (C2H5O)3P + ·OH → Products                     2
  Reference reaction:  alpha-pinene + ·OH → Products 2
    2006ASC/LON7393-7400   (C2H5O)3PO + ·OH → Products                     2
  Reference reaction:  1,3,5-Trimethylbenzene + ·OH → Products 2
    2006ASC/LON7393-7400   ·OH + (CH3O)2P(O)C2H5 → Products                     2
  Reference reaction:  (CH3O)2P(O)CH3 + ·OH → Products 2
    2006ASC/LON7393-7400   (C2H5O)3P + ·OH → Products                     2
  Reference reaction:  (C2H5O)2P(O)CH3 + ·OH → Products 2

Search returned 15 records.