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Author(s):   Barker, J.R.; Stimac, P.J.; King, K.D.; Leitner, D.M.
Title:   CF3CH3 -> HF+CF2CH2: A non-RRKM reaction?
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   2944 - 2954
Year:   2006
Reference type:   Journal article
Squib:   2006BAR/STI2944-2954

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Temperature:   300 - 2400 K
Pressure:  2.00E-2 - 4.00 bar
Rate expression:   no rate data available
Category:  Theory
Data type:   Other theoretical
Pressure dependence:   Rate constant is pressure dependent
Comments:   RRKM and non-RRKM / Master Equation modeling of experimental literature data on thermal and chemically activated decomposition of 1,1,1-trifluoroethane was performed. Rate constants were calculated for wide ranges of temperatures and pressures. However, no rate expressions or tabulated values of rate constants are given in the article.

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