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Author(s):   Blitz, M.A.; Hughes, K.J.; Pilling, M.J.; Robertson, S.H.
Title:   Combined experimental and master equation investigation of the multiwell reaction H+SO2
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   2996 - 3009
Year:   2006
Reference type:   Journal article
Squib:   2006BLI/HUG2996-3009

Reaction:   SO2 + → HSO2
Reaction order:   2
Temperature:   295 - 423 K
Pressure:  3.00E13 - 2.30E14 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Rate constant is pressure and temperature dependent. Values at individual pressures and temperatures are given in a table. These results were used to develop a master equation model of the reaction.

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