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Author(s):   Butkovskaya, N.I.; Pouvesle, N.; Kukui, A.; Mu, Y.J.; Le Bras, G.
Title:   Mechanism of the OH-initiated oxidation of hydroxyacetone over the temperature range 236-298 K
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   6833 - 6843
Year:   2006
Reference type:   Journal article
Squib:   2006BUT/POU6833-6843

Reaction:   ·CH(OH)C(O)CH3 + O2HCOOH + CO2 + ·CH3
Reaction order:   2
Temperature:   298 K
Pressure:  0.27 bar
Rate expression:   1.4x10-13 [cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Turbulent flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry

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