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Chemical Sciences Division
Chen, Z.M.;Wang, C.X.|
Rate constants of the gas-phase reactions of CH3OOH with O3 and NOx at 293 K
Chem. Phys. Lett.
233 - 238
CH3OOH + NO2 → Products
Pressure: 1.01 bar
9.6x10-21 [±1.3x10-21 cm3/molecule s]
Absolute value measured directly
Static or low flow - Data taken vs time
By end product analysis
Fourier transform (FTIR)
Decays of methyl hydroperoxide were followed by FTIR spectroscopy at 1320 cm-1 in a smog chamber containing a bath gas of nitrogen or synthetic air.
CH3ONO2 was identified as the major product of reaction.
Listed uncertainties are statistical only and are 2 standard deviations.
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