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Accessibility information
Author(s):   Chen, Z.M.;Wang, C.X.
Title:   Rate constants of the gas-phase reactions of CH3OOH with O3 and NOx at 293 K
Journal:   Chem. Phys. Lett.
Volume:   424
Page(s):   233 - 238
Year:   2006
Reference type:   Journal article
Squib:   2006CHE/WAN233-238

Reaction:   CH3OOH + NO → Products
Reaction order:   2
Temperature:   293 K
Pressure:  1.01 bar
Rate expression:   8.6x10-22 [cm3/molecule s]
Rate constant is an upper limit.
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Decays of methyl hydroperoxide were followed by FTIR spectroscopy at 1320 cm-1 in a smog chamber containing a bath gas of nitrogen or synthetic air.

No reaction products were identified.


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