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Author(s):   Cometto, P.M.; Teruel, M.A.; Taccone, R.A.; Lane, S.I.
Title:   Absolute rate determinations and temperature dependences of the gas-phase reactions of O with halogenated propenes
Journal:   Chem. Phys. Lett.
Volume:   417
Page(s):   480 - 485
Year:   2006
Reference type:   Journal article
Squib:   2006COM/TER480-485

Reaction:   CF3CF=CF2 + → Products
Reaction order:   2
Temperature:   298 - 363 K
Pressure:  2.37E-3 - 5.03E-3 bar
Rate expression:   1.57x10-11 [±7.2x10-12 cm3/molecule s] e-15600 [±1300 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Chemiluminescence
Comments:   Error limits are 2 sigma (random errors only).

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.89E-14
300 3.02E-14
325 4.88E-14
350 7.38E-14
363 8.94E-14