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Chemical Sciences Division
Czarnowski, J.;Cobos, C.J.|
Formation of perfluorobutene-2 epoxide in the thermal gas-phase reaction of perfluorobutene-2 with nitrogen dioxide. An experimental and DFT study
Z. Phys. Chem.
1595 - 1608
2-C4F8 (unspecified) + NO2 → Perfluorobutene-2 epoxide + NO
no rate data available
Reaction potential energy surface was studied using quantum chemistry and product channels were analyzed. No rate constant values were calculated.
In the experimental part of the work, the reaction between perfluorobutene-2 and NO2 was studied between 418.5 and 470 K. Formation of perfluorobutene-2 epoxide and NO was observed at lower temperature while at higher temperatures the perfluorobutene-2 epoxide product decomposes to CF3CFO and the CF3CF biradical. No rate constant values were derived.
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