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Author(s):   Dillon, T.J.; Blitz, M.A.; Heard, D.E.
Title:   Determination of the rate coefficients for the reactions IO+NO2+M(Air)->+IONO2+M and O(P-3)+NO2 -> O-2+NO using laser-induced fluorescence spectroscopy
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   6995 - 7002
Year:   2006
Reference type:   Journal article
Squib:   2006DIL/BLI6995-7002

Reaction:   NO2 + O2 + NO
Reaction order:   2
Temperature:   294 K
Pressure:  6.67E-2 - 0.13 bar
Rate expression:   9.3x10-12 [±9.0x10-13 cm3/molecule s]
Rate constant is an upper limit.
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   From a fit to O-atom decay in a system containing NO2 and CF3I. The main purpose of the study was to measure the IO + NO2 rate constant.

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