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Author(s):   Farkas, E.; Kovacs, G.; Szilagyi, I.; Dobe, S.; Berces, T.; Marta, F.
Title:   Rate constant for the reaction of CH3C(O)CH2 radical with HBr and its thermochemical implication
Journal:   Int. J. Chem. Kinet.
Volume:   38
Page(s):   32 - 37
Year:   2006
Reference type:   Journal article
Squib:   2006FAR/KOV32-37

Reaction:   CH3C(O)CH2(·) + HBr(CH3)2CO + Br·
Reaction order:   2
Temperature:   298 K
Pressure:  3.55E-3 bar
Rate expression:   3.04x10-14 [±1.99x10-15 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Laser induced fluorescence

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