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Author(s):   Ham, J.E.; Proper, S.P.; Wells, J.R.
Title:   Gas-phase chemistry of citronellol with ozone and OH radical: Rate constants and products
Journal:   Atmos. Environ.
Volume:   40
Page(s):   726 - 735
Year:   2006
Reference type:   Journal article
Squib:   2006HAM/PRO726-735

Reaction:   Citronellol + ·OH → Products
Reaction order:   2
Temperature:   297 K
Pressure:  1.01 bar
Rate expression:   1.7x10-10 [±4.3x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   OH radicals generated by photolysis of methyl nitrite in the presence of NO.
Individul relative rate measurements put on absolute basis with k(limonene) = 1.64±0.41x10-10 cm3s-1 and k(3-carene) = 8.8±2.2x10-11 cm3s-1.
Extensive product analysis also carried out.

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