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Author(s):   Hoyermann, K.; Nothdurft, J.; Olzmann, M.; Wehmeyer, J.; Zeuch, T.
Title:   Formation and decomposition of chemically activated cyclopentoxy radicals from the c-C5H9+O reaction
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   3165 - 3173
Year:   2006
Reference type:   Journal article
Squib:   2006HOY/NOT3165-3173

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2006HOY/NOT3165-3173   Cyclopentyl + → Products  298   1.67           1.67  2
  Reference reaction:  ·C2H5 + → Products 2
  2006HOY/NOT3165-3173   Cyclopentyl + → Products  298   1.32           1.32  2
  Reference reaction:  CH3OCH2 + → Products 2
  2006HOY/NOT3165-3173   Cyclopentyl + → Products  298   2.87E-10           2.87E-10  2
  2006HOY/NOT3165-3173   Cyclopentyl + → Products  298   2.87E-10           2.87E-10  2
  2006HOY/NOT3165-3173   Cyclopentyl + → cyclopentoxy (chemically activated)  298   0.68           0.68  2
  Reference reaction:  Cyclopentyl + → Products 2
  2006HOY/NOT3165-3173   Cyclopentyl + → Products + ·OH  298   0.32           0.32  2
  Reference reaction:  Cyclopentyl + → Products 2
  2006HOY/NOT3165-3173   cyclopentoxy (chemically activated) → Cyclopentanone +   298   0.31           0.31  1
  Reference reaction:  cyclopentoxy (chemically activated) → Products 1
  2006HOY/NOT3165-3173   cyclopentoxy (chemically activated) → CH2=CHCH2CH2CHO +   298   0.40           0.40  1
  Reference reaction:  cyclopentoxy (chemically activated) → Products 1
  2006HOY/NOT3165-3173   cyclopentoxy (chemically activated) → C2H4 + C2H4 + CO +   298   0.17           0.17  1
  Reference reaction:  cyclopentoxy (chemically activated) → Products 1
  2006HOY/NOT3165-3173   cyclopentoxy (chemically activated) → C2H4 + CH2=CHCHO +   298   0.12           0.12  1
  Reference reaction:  cyclopentoxy (chemically activated) → Products 1
  2006HOY/NOT3165-3173   Cyclopentene + → Products + C2H4  298   0.24           0.24  2
  Reference reaction:  Cyclopentene + → Products 2
  2006HOY/NOT3165-3173   Cyclopentene + → Products + CH2=CHCHO  298   0.18           0.18  2
  Reference reaction:  Cyclopentene + → Products 2
  2006HOY/NOT3165-3173   Cyclopentene + Cyclopentanone  298   0.29           0.29  2
  Reference reaction:  Cyclopentene + → Products 2
  2006HOY/NOT3165-3173   Cyclopentene + cyclopentene epoxide  298   0.23           0.23  2
  Reference reaction:  Cyclopentene + → Products 2
  2006HOY/NOT3165-3173   Cyclopentene + CH2=CHCH2CH2CHO  298   0.06           0.06  2
  Reference reaction:  Cyclopentene + → Products 2
  2006HOY/NOT3165-3173   cyclopentyloxy → Cyclopentanone +   298   1.32E13       7.75E04   0.34  1
  2006HOY/NOT3165-3173   cyclopentyloxy → (·)CH2(CH2)3CHO  298   1.32E13       3.50E04   9.68E06  1
  2006HOY/NOT3165-3173   (·)CH2(CH2)3CHO → cyclopentyloxy  298   1.00E11       4.86E04   303  1
  2006HOY/NOT3165-3173   (·)CH2(CH2)3CHO → CH2=CHCH2CH2CHO +   298   5.89E12       1.51E05   2.01E-14  1
  2006HOY/NOT3165-3173   (·)CH2(CH2)3CHO → C2H4 + ·CH2CH2CHO  298   3.98E13       1.30E05   6.51E-10  1

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