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Author(s):   Le Crane, J.P.; Rayez, M.T.; Rayez, J.C.; Villenave, E.
Title:   A reinvestigation of the kinetics and the mechanism of the CH3C(O)O-2+HO2 reaction using both experimental and theoretical approaches
Journal:   Phys. Chem. Chem. Phys.
Volume:   8
Page(s):   2163 - 2171
Year:   2006
Reference type:   Journal article
Squib:   2006LEC/RAY2163-2171

Reaction:   HO2 + CH3C(O)OO(·)·OH + O2 + CH3C(O)O
Reaction order:   2
Reference reaction:   HO2 + CH3C(O)OO(·) → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  2.40E14 bar
Rate expression:   1.0x10-1
Rate constant is an upper limit.
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

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