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Author(s):   Li, Z.J.; Pirasteh, A.
Title:   Kinetic study of the reactions of atomic chlorine with several volatile organic compounds at 240-340 K
Journal:   Int. J. Chem. Kinet.
Volume:   38
Page(s):   386 - 398
Year:   2006
Reference type:   Journal article
Squib:   2006LI/PIR386-398

Reaction:   1,4-Dioxane + ·Cl → Products
Reaction order:   2
Temperature:   240 - 340 K
Pressure:  1.33E-3 - 1.47E-3 bar
Rate expression:   1.93x10-10 [±2.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   Based on k(Cl + CH3OCH3) = (1.91±0.20)x10-10cm3s-1.

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