Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Li, Z.J.; Pirasteh, A.
Title:   Kinetic study of the reactions of atomic chlorine with several volatile organic compounds at 240-340 K
Journal:   Int. J. Chem. Kinet.
Volume:   38
Page(s):   386 - 398
Year:   2006
Reference type:   Journal article
Squib:   2006LI/PIR386-398

Reaction:   1,4-Dioxane + ·Cl → Products
Reaction order:   2
Temperature:   240 - 340 K
Pressure:  1.33E-3 - 1.47E-3 bar
Rate expression:   1.93x10-10 [±2.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   Based on k(Cl + CH3OCH3) = (1.91±0.20)x10-10cm3s-1.

View full bibliographic record.