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Author(s):   McCunn, L.R.; Lau, K.C.; Krisch, M.J.; Butler, L.J.; Tsung, J.W.; Lin, J.J.
Title:   Unimolecular dissociation of the CH3OCO radical: An intermediate in the CH3O+COreaction
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   1625 - 1634
Year:   2006
Reference type:   Journal article
Squib:   2006MCC/LAU1625-1634

Reaction:   CH3OC(·)(O) → CO + CH3
Reaction order:   1
Reference reaction:   CH3OC(·)(O) → Products
Reference reaction order:   1
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   Branching in decomposition of highly vibrationally excited CH3OCO was studied. No thermal rate constants or branching fractions were obtained.

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