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Author(s):   Monsalve, A.; Rosas, F.; Tosta, M.; Herize, A.; Dominguez, R.M.; Brusco, D.; Chuchani, G.
Title:   The elimination kinetics and mechanisms of ethyl piperidiner-3-carboxylate, ethyl 1-methylpiperidine-3-carboxylate, and ethyl 3-(piperidin-1-yl) propionate in the gas phase
Journal:   Int. J. Chem. Kinet.
Volume:   38
Page(s):   106 - 114
Year:   2006
Reference type:   Journal article
Squib:   2006MON/ROS106-114

Reaction:   1-Piperidinepropanoic acid, ethyl esterC2H4 + CO2 + Piperidine, 1-ethyl-
Reaction order:   1
Temperature:   642 - 694 K
Pressure:  6.00E-2 - 0.11 bar
Rate expression:   6.17x1012 [s-1] e-199700 [±2000 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   In both real time and by end product analysis
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
642 3.52E-4
650 5.53E-4
675 2.17E-3
694 5.80E-3