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Author(s):   Oehlschlaeger, M.A.;Davidson, D.F.;Hanson, R.K.
Title:   Experimental investigation of toluene plus H → benzyl plus H2 at high temperatures
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   9867 - 9873
Year:   2006
Reference type:   Journal article
Squib:   2006OEH/DAV9867-9873

Reaction:   Toluene + H2 + Benzyl
Reaction order:   2
Temperature:   1256 - 1667 K
Pressure:  1.57 - 1.90 bar
Rate expression:   2.21x10-9 [cm3/molecule s] e-62258 [J/mole]/RT
Uncertainty:   0.25
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Quoted uncertainty (25%) is two sigma.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1256 5.69E-12
1275 6.22E-12
1300 6.96E-12
1325 7.76E-12
1350 8.61E-12
1375 9.53E-12
1400 1.05E-11
1425 1.15E-11
1450 1.26E-11
1475 1.38E-11
1500 1.50E-11
1525 1.63E-11
1550 1.76E-11
1575 1.90E-11
1600 2.05E-11
1625 2.20E-11
1650 2.36E-11
1667 2.47E-11