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Author(s):   Sellevag, S.R.; Nyman, G.; Nielsen, C.J.
Title:   Study of the carbon-13 and deuterium kinetic isotope effects in the Cl and OH reactions of CH4 and CH3Cl
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   141 - 152
Year:   2006
Reference type:   Journal article
Squib:   2006SEL/NYM141-152

Reaction:   CH3Cl + ·OH·CH2Cl + H2O
Reaction order:   2
Reference reaction:   ·OH + CHD2Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.03±5.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Uncerainties are 2 sigma increased by 50% to account for the uncertainty of spectral analysis.

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