Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Sellevag, S.R.; Nyman, G.; Nielsen, C.J.
Title:   Study of the carbon-13 and deuterium kinetic isotope effects in the Cl and OH reactions of CH4 and CH3Cl
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   141 - 152
Year:   2006
Reference type:   Journal article
Squib:   2006SEL/NYM141-152

Reaction:   CH3Cl + ·OH·CH2Cl + H2O
Reaction order:   2
Reference reaction:   ·OH + CHD2Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   2.03±5.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Uncerainties are 2 sigma increased by 50% to account for the uncertainty of spectral analysis.

View full bibliographic record.