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Accessibility information
Author(s):   Zhu, L.; Bozzelli, J.W.
Title:   Kinetics of the multichannel reaction of methanethiyl radical (CH3S center dot) with O-3(2)
Journal:   J. Phys. Chem. A
Volume:   110
Page(s):   6923 - 6937
Year:   2006
Reference type:   Journal article
Squib:   2006ZHU/BOZ6923-6937

Reaction:   CH3S(O)2 → ·CH3 + SO2
Reaction order:   2
Temperature:   300 - 2000 K
Rate expression:   9.49x10-11 [cm3/molecule s] (T/298 K)0.57 e-61923 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using canonical transition state theory.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.58E-21
400 9.22E-19
500 4.34E-17
600 5.77E-16
700 3.72E-15
800 1.52E-14
900 4.57E-14
1000 1.11E-13
1100 2.31E-13
1200 4.26E-13
1300 7.20E-13
1400 1.13E-12
1500 1.68E-12
1600 2.37E-12
1700 3.23E-12
1800 4.26E-12
1900 5.47E-12
2000 6.85E-12