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Author(s):   Anderson, R.S.;Huang, L.;Iannone, R.;Rudolph, J.
Title:   Laboratory measurements of the 12C/13C kinetic isotope effects in the gas-phase reactions of unsaturated hydrocarbons with Cl atoms at 298 +/- 3 K
Journal:   J. Atmos. Chem.
Volume:   56
Page(s):   275 - 291
Year:   2007
Reference type:   Journal article
Squib:   2007AND/HUA275-291

Reaction:   Ethylbenzene + Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.00 bar
Rate expression:   1.15x10-10 [±4.0x10-12 cm3/molecule s]
Category:  Uncategorized
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   Authors also report 12C/13C kinetic isotope effects for reaction with Cl.

Absolute value based on measured relative rate and k(Cl + o-xylene) = (1.35 +/- 0.21) x 10-10 cm3 molecule-1 s-1

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