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Title: A comparison of the reactivity of germylene and dimethylgermylene with some methylgermanes. Direct kinetic and quantum chemical studies
Journal: Phys. Chem. Chem. Phys.
Volume: 9
Page(s): 4395 - 4406
Year: 2007
Reference type: Journal article
Squib: 2007BEC/BOG4395-4406
Reaction:
CH3GeH3 + :GeH2 → CH3GeH2GeH3
Reaction order:
2
Temperature:
296
K
Pressure: 1.33E-2 bar
Rate expression:
1.33x10-10 [±4.0x10-12 cm3/molecule s] e7350 [±480 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
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