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Author(s):   Blanco, M.B.; Teruel, M.A.
Title:   Atmospheric degradation of fluoroesters (FESs): Gas-phase reactivity study towards OH radicals at 298 K
Journal:   Atmos. Environ.
Volume:   41
Page(s):   7330 - 7338
Year:   2007
Reference type:   Journal article
Squib:   2007BLA/TER7330-7338

Reaction:   CF3C(O)OCH3 + ·OH → Products
Reaction order:   2
Temperature:   296 K
Pressure:  1.00 bar
Rate expression:   4.97x10-14 [±1.04x10-14 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   CH3Cl and ethane were used as reference reactants. Both nitrogen and synthetic air were used as bath gases. Uncertainties are twice the standard deviation with added effect of the uncertainties of the rate constants of the reference reactions. The abstract and the text give the rate constant units as cm3 mol-1 s-1, although the authors, apparently, mean cm3 molecule-1 s-1.

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