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Accessibility information
Author(s):   Cassanelli, P.; Fox, D.J.; Cox, R.A.
Title:   Temperature dependence of pentyl nitrate formation from the reaction of pentyl peroxy radicals with NO
Journal:   Phys. Chem. Chem. Phys.
Volume:   9
Page(s):   4332 - 4337
Year:   2007
Reference type:   Journal article
Squib:   2007CAS/FOX4332-4337

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2007CAS/FOX4332-4337   NO + CH3(CH2)3CH2OO· → 1-pentoxy radical + NO2  261 - 305   2900       -1.33E04   6.22E05  2
  Reference reaction:  NO + CH3(CH2)3CH2OO· → Nitric acid, pentyl ester 2
  2007CAS/FOX4332-4337   CH3CH2CH2CH(OO·)CH3 + NO → 2-pentoxy radical + NO2  261 - 305   350       -9400   1.55E04  2
  Reference reaction:  CH3CH2CH2CH(OO·)CH3 + NO → n-C3H7CH(CH3)NO3 2
  2007CAS/FOX4332-4337   (CH3)2C(OO·)CH2CH3 + NO → CH3CH2C(CH3)2O(·) + NO2  261 - 305   960       -1.20E04   1.22E05  2
  Reference reaction:  (CH3)2C(OO·)CH2CH3 + NO → C2H5C(CH3)2ONO2 2

Search returned 3 records.