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Author(s):   Cassanelli, P.; Fox, D.J.; Cox, R.A.
Title:   Temperature dependence of pentyl nitrate formation from the reaction of pentyl peroxy radicals with NO
Journal:   Phys. Chem. Chem. Phys.
Volume:   9
Page(s):   4332 - 4337
Year:   2007
Reference type:   Journal article
Squib:   2007CAS/FOX4332-4337

Reaction:   CH3CH2CH2CH(OO·)CH3 + NO → 2-pentoxy radical + NO2
Reaction order:   2
Reference reaction:   CH3CH2CH2CH(OO·)CH3 + NO → n-C3H7CH(CH3)NO3
Reference reaction order:   2
Temperature:   261 - 305 K
Pressure:  1.01 bar
Rate expression:   3.5x102 e9400 [±3900 J/mole]/RT
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In both real time and by end product analysis
Analytical technique:   Gas chromatography
Comments:   CH3(CH2)3CH2OO is 2-Pentyl peroxy redical

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
261 2.66E4
275 2.14E4
300 1.52E4
305 1.43E4